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Synthesis of cis-1,2-dichlorovinylsulfones via Fe-catalyzed regio- and stereoselective addition of sulfonyl chlorides to aromatic chloroalkynes

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First Author : Lina Wang

Date of Publication : 2014-01-01

Journal : Tetrahedron Letters

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.55

Issue : No.5

Page Number : 1011-1013

ISSN : 0040-4039

Key Words : 1,2-Dihaloalkenes;Chloroalkynes;Iron;Sulfonyl;chlorides;Stereoselectivity

Abstract : An iron-catalyzed regio- and stereoselective chlorosulfonylation of aryl chloroalkynes has been described, producing cis-1,2-dichlorovinylsulfones in satisfactory yields with good to excellent stereoselectivity ( Z/E up to 95:5). A variety of functional g

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