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Copper-catalyzed trans-carbohalogenation of terminal alkynes with functionalized tertiary alkyl halides.

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First Author : Che C

Date of Publication : 2015-01-01

Journal : Organic Letters

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.17

Issue : No.6

Page Number : 1617-1620

Abstract : A highly trans-selective Cu-catalyzed carbohalogenation including carbobromination, carboiodination, and carbochlorination of terminal alkynes with activated tertiary alkyl halides has been realized, providing quaternary-carbon-containing alkenyl halides

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