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Copper-catalyzed regio- and stereoselective hydroallylation of thioalkynes with allylboronates: a facile and convenient synthesis of 1,4-dienes

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First Author : Wei Kong

Date of Publication : 2015-01-01

Journal : Tetrahedron Letters

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.56

Issue : No.21

Page Number : 2780-2782

ISSN : 0040-4039

Key Words : Thioalkyne;Hydroallylation;Copper;1,4-Diene

Abstract : A Cu-catalyzed, highly regio-, and stereoselective hydroallylation of thioalkynes has been developed with allylboronates as the allylating reagents, providing stereodefined 1,4-dienyl sulfides in good to excellent yields under very mild reaction condition

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