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Pd-Catalyzed Regio- and Stereoselective Addition of Boronic Acids to Silylacetylenes: A Stereodivergent Assembly of beta,beta-Disubstituted Alkenylsilanes and Alkenyl Halides

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First Author : Kong, W

Date of Publication : 2014-01-01

Journal : The Journal of Organic Chemistry

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.79

Issue : No.12

Page Number : 5799-5805

ISSN : 0022-3263

Abstract : An efficient Pd-catalyzed addition of boronic acids to silylacetylenes is described, providing beta,beta-disubstituted (E)- or (Z)-alkenylsilanes in satisfactory yields with excellent regio- and stereoselectivity under mild reaction conditions. It represe

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