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An unprecedented Pd-catalyzed trans-addition of boronic acids to ynamides.

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First Author : Yang Y

Date of Publication : 2014-01-01

Journal : Chem Commun (Camb)

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.50

Issue : No.18

Page Number : 2347-2349

ISSN : 1359-7345

Abstract : An unprecedented Pd-catalyzed trans-addition of boronic acids to ynamides has been reported, giving α,β-disubstituted enamides in high yields with excellent regio- and stereoselectivity. A possible mechanism involving the palladium carbene intermediate ha

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