2021.01起任 Frontiers in Chemistry杂志的评审编辑（Review Editor）

2020.07至今：双龙学者特聘教授，浙江师范大学生化学院

2016.102020.05: 博士后，新加坡南洋理工大学，导师：Jianrong Steve Zhou

2011.09 2016.07：博士， 四川大学化学学院，导师：游劲松 教授

2007.09  2011.07：理学学士， 武汉大学化学与分子科学学院

科研项目：

1）2022-2024，砜试剂参与的过渡金属催化多组分SO2插入反应构筑手性砜化合物的研究，国家自然科学基金青年科学基金项目，30万， 主持

2）2022-2024，α-手性砜的不对称合成及其在药物分子合成中的应用研究，浙江省自然科学基金青年探索项目，10万， 主持

3）2021-2025，浙江师范大学“双龙学者”科研启动经费，30万，主持

发表论文：

1) Palladium-Catalyzed Intermolecular 1,3-Dienylation of Propargyl Esters Involving the Insertion of SO2

H. Jiang, M. Yu, S. Zhang, L. Jin, Y. Zhang, X. Huang,* Org. Lett. 2025, 27, 2220-2227.

2) Diaryliodonium Salt-Mediated Radical Transformation of Indoles with Alcohols for the Synthesis of Unsymmetrical Bis(indolyl)methanes

H. Wang, H. Jiang, S. Lin, S. Zhang, X. Huang,* Adv. Synth. Catal. 2024, 366, 4765-4771.

3) Selective 1,1- and 1,2-Dibromination of the Phenylethanes in the Presence of NaBr/NaBrO3/H2SO4 as the Bromination Reagent

H. Jiang,‡ K. Jin,‡ X. Lin,‡ M. Yu, X. Xiao,* X. Huang,* Org. Biomol. Chem. 2024, 22, 6960-6965.

4) Direct C−H Sulfonylation of Hydrazones Involving the Insertion of SO2

M. Yu, S. Lin, S. Zhang, X. Lin, X. Huang,* Org. Chem. Front. 2024, 11, 4284-4289.

5) Palladium-Catalyzed C2-Selective Direct Arylation of Benzo[b]thiophene 1,1-Dioxides with Arylboronic Acids

X. Zhang, Y. Lu, H. Wang, M. Chen, S. Lin, X. Huang,* ACS Omega 2024, 9, 1738-1747.

6) Benzotriazolium Ylides-Assisted Multicomponent Diastereoselective Synthesis of Activated Tetra- and PentaSubstituted Cyclopropanes

Y. Xia, Q. Zhang, X. Lin, S. Lin, X. Ma, X. Xiao,* X. Huang,* Asian J. Org. Chem. 2024, 13, e202400012.

7) Palladium-catalyzed α-arylation/β-elimination of sulfones

M. Yu, L. Duan, X. Zhang, Q. Zhang, H. Wang, X. Huang,* New J. Chem. 2024,48, 1062-1066.

8) Palladium-catalyzed domino cyclization/direct functionalization involving the insertion of SO2

X. Zhang, Y. Lu, S. Zhang, S. Lin, M. Chen, X. Huang,* New J. Chem. 2024, 48, 5101-5106.

9) Photoredox-catalyzed sulfonylation of diaryliodonium salts with DABSO and silyl enolates involving the insertion of SO2

S. Zhang, Q. Zhang, S. Lin, X. Lin, X. Huang,* RSC Adv. 2024, 14, 14697-14701.

10) Palladium-Catalyzed Reductive Cross-Coupling of Propargyl Acetates with Aryl Iodides Involving the Insertion of SO2

Q. Zhang, Y. Ying, H. Zhang, L. Xu, X. Lin, X. Huang,* Chin. J. Org. Chem. 2024, 44, 2033-2040.

11) Pd-Catalyzed Reductive Cross-Coupling of Allylic Esters with Aryl Iodides Involving the Insertion of SO2

X. Zhang, S. Lin, X. Huang,* Chin. J. Org. Chem. 2024, doi: 10.6023/cjoc202404019.

12) Palladium-Catalyzed C2-Selective Oxidative Olefination of Benzo[b]thiophene 1，1-Dioxides with Styrenes and Acrylates

B. Yang, Y. Lu, L. Duan, X. Ma, Y. Xia, X. Huang,* ACS Omega 2023, 8, 10100-10110.

13) Nickel-Catalyzed Heck Reaction of Cycloalkenes with Inert C—O Bonds of Aryl Carbonates and Aryl Sulfamates

X. Zeng, Q. Zhang, X. Wu, J. Zhang, X. Zhang, X. Huang,* Chin. J. Org. Chem. 2022, 42, 2981-2987.

14) 1，1，2-Tribromoethyl arenes: novel and highly efficient precursors for the synthesis of 1-bromoalkynes and α-bromoketones

X. Lin, C. Fang, X. Huang,* X. Xiao,* Org. Chem. Front. 2021, 8, 4387-4391.

15) Enantioselective Intermolecular Heck and Reductive Heck Reactions of Aryl Triflates, Mesylates, and Tosylates Catalyzed by Nickel

X. Huang, S. Teng, Y. R. Chi, W. Xu, M. Pu, Y.-D. Wu, J. S. Zhou,* Angew. Chem. Int. Ed. 2021, 60, 2828-2832.

16) Nickel-catalyzed Heck reaction of cycloalkenes using aryl sulfonates and pivalates

J. S. Zhou,* X. Huang, S. Teng, Y. R. Chi, Chem. Commun. 2021, 57, 3933-3936.

17) Asymmetric Reductive and Alkynylative Heck Bicyclization of Enynes to Access Conformationally Restricted Aza[3.1.0]bicycles

X. Huang, M. H. Nguyen, M. Pu, L. Zhang, Y. R. Chi, Y.-D.,Wu, J. S. Zhou,* Angew. Chem. Int. Ed. 2020, 59, 10814.

18) Palladium-Catalyzed Enantioselective Arylation of Racemic Ketones to Form Bridged Bicycles via Dynamic Kinetic Resolution

X. Huang, W. R. J. J. Oh, J. S. Zhou,* Angew. Chem. Int. Ed. 2018, 57, 7673.

19) N-Oxide as a Traceless Oxidizing Directing Group: Mild Rhodium(III)-Catalyzed C–H Olefination for the Synthesis of ortho-Alkenylated Tertiary Anilines

X. Huang, J. Huang, C. Du, X. Zhang, F. Song, J. You,* Angew. Chem. Int. Ed. 2013, 52, 12970.

20) Rhodium(III)-Catalyzed Activation of C_sp3–H Bonds and Subsequent Intermolecular Amidation at Room Temperature

X. Huang, Y. Wang, J. Lan, J. You,* Angew. Chem. Int. Ed. 2015, 54, 9404.

21) Rhodium(III)-Catalyzed C(sp3)−H Amidation of 8-Methylquinolines with Amides at Room Temperature

X. Huang, J. You,* Chem. Lett. 2015, 44, 1685.

22) Rh(III)-Catalyzed Chemoselective C–H Functionalizations of Tertiary Aniline N-Oxides with Alkynes

X. Huang, W. Liang, Y. Shi , J. You,* Chem. Commun. 2016, 52, 6253.

23) Rh(III)-Catalyzed Annulation of N-Methoxybenzamides with Ynesulfonamides at Room Temperature: A Practical and Efficient Route to 4-Aminoisoquinolone Derivatives

G. Tan,‡ X. Huang,‡ Q. Wu, L. Zhang, J. You,* RSC Adv. 2014, 4, 49186. (共同一作)

24) Ruthenium-Catalyzed Intermolecular Direct Silylation of Unreactive C(sp3)–H Bonds

W. Li, X. Huang, J. You,* Org. Lett., 2016, 18, 666.

25) Cobalt-Catalyzed Oxidative C-H/C-H Cross-Coupling between Two Heteroarenes

G. Tan, S. He, X. Huang, X. Liao, Y. Cheng, J. You,* Angew. Chem. Int. Ed. 55, 10414. 

26) Nickel-Catalyzed Chelation-Assisted Direct Arylation of Unactivated C(sp3)–H Bonds with Aryl Halides

M. Li, J. Dong, X. Huang, K. Li, Q. Wu, F. Song, J. You,* Chem. Commun. 2014, 50, 3944.

27) Aerobic Ru-Catalyzed Direct C2-Olefination of N-Heteroarenes with Alkenes Directed by a Removable N-Dimethylcarbamoyl Group

L.-Q. Zhang, S. Yang, X. Huang, J. You,* F. Song,* Chem. Commun. 2013, 49, 8830.

28) A General Method to Diverse Cinnolines and Cinnolinium Salts

D. Zhao, Q. Wu, X. Huang, F. Song, T. Lv, J. You,* Chem. Eur. J. 2013, 19, 6239.

29) Chelation-Assisted Rh(III)-Catalyzed C2-Selective Oxidative C–H/C–H Cross-Coupling of Indoles/Pyrroles with Heteroarenes

X. Qin, H. Liu, D. Qin, Q. Wu, J. You,* D. Zhao, Q. Guo, X. Huang, J. Lan,* Chem. Sci. 2013, 4, 1964.

30) Regiospecific Synthesis of 1,2-Disubstituted (Hetero)aryl Fused Imidazoles with Tunable Fluorescent Emission

D. Zhao, J. Hu, N. Wu, X. Huang, X. Qin, J. Lan, J. You,* Org. Lett. 2011, 13, 6516.

31) Asymmetric Stepwise Reductive Amination of Sulfonamides, Sulfamates, and a Phosphinamide by Nickel Catalysis

X. Zhao, H. Xu, X. Huang, J. S. Zhou,* Angew. Chem. Int. Ed. 2019, 58, 292.

申请专利

1）黄晓雷; 王洪贞; 蒋浩浩; 张硕硕，一种二吲哚基甲烷的制备方法，CN202410665196.X

2）黄晓雷; 张倩; 张鑫伟; 蒋浩浩; 王洪贞; 余孟沼，一种利用SO2插入的多组分偶联反应制备炔丙基砜的方法，CN202211661283.5

3）黄晓雷; 卢瑶瑶; 张鑫伟; 段璐琼; 张倩，一种利用氧化型Suzuki偶联反应制备2-芳基苯并噻吩砜的方法，CN202211653645.6

4）黄晓雷; 杨冰彬; 卢瑶瑶; 夏垚林; 马小玉，一种含噻吩砜-烯烃结构单元的荧光材料及其制备方法，CN202211386879.9

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