史乐，男，1994年2月生，博士，浙江师范大学“双龙学者”特聘教授，研究生导师。2020年博士毕业于南京大学化学化工学院，导师王新益教授，2021年-2022年于波兰雅盖隆大学从事博士后研究，2022年-2024年在浙江大学化学系从事博士后研究，合作导师为陈志杰研究员和黄飞鹤教授，2024年11月加入浙江师范大学多功能框架材料研究院（团队负责人：陈邦林教授），研究方向为功能性金属有机框架材料的设计合成及其应用研究。近五年以第一作者（含共一）或通讯作者在Nature、Nat. Synth.、Chem、Matter、Angew. Chem. Int. Ed.、Sci. China. Chem.、Inorg. Chem.等权威期刊上发表多篇学术论文，入选浙江省青年人才托举培养项目。

学习和工作经历

2024.11-至今，浙江师范大学，化学与材料科学学院，“双龙学者”特聘教授

2022.09-2024.09 浙江大学，化学系，博士后

2021.01-2022.06 雅盖隆大学，化学系，博士后

2015.09-2020.06 南京大学，化学化工学院，博士

2011.09-2015.06 安徽科技学院，化学与材料工程学院，学士

科研项目

1. 浙江省自然科学基金青年项目，在研

2.浙江省青年人才托举培养项目，在研

3. 浙江师范大学双龙学者启动经费，在研

代表性论文

(1)  Y. Wu^†, L. Shi^†, L. Xu^†, J. Yang, X. Miao, B. Hua*, Z. Chen*, J. L. Sessler*, and F. Huang*, Nature, 2025, 640, 676-682.

(2)  L. Shi, Y. Zhong, H. Cao, H. Wang, Z. Xiong, K. Wang, H, Shen and Z. Chen*,  Nat. Synth., 2024, 3, 1560-1566.

(3)  L. Shi, Z. Xiong, H. Wang, H. Cao and Z. Chen*, Chem, 2024, 10, 2464-2472

(4)  L. Shi, K. O. Kirlikovali, Z. Chen* and O. K. Farha*, Chem, 2024, 10, 484-503.

(5)  D. Wang, L. Shi*, and J. Li*,  Matter, 2025, 8, 101949.

(6)  L. Shi, D. Shao, X.-Q. Wei, K. R. Dunbar*, X.-Y. Wang*,  Angew. Chem. Int. Ed., 2020, 59, 10379-10384.

论文列表

2025年

(57) Y. Wu^†, L. Shi^†, L. Xu^†, J. Yang, X. Miao, B. Hua*, Z. Chen*, J. L. Sessler*, and F. Huang*, Supramolecular docking structure determination of alkyl-bearing molecules, Nature, 2025, 640, 676-682.

(56) S. Ma, Y. Lam, L. Shi, J. Yang, K. Wang, B. Yu, C. Kan, B. Fei, J. H. Xin, K. Ma*,  J. F. Stoddart* and Zhijie Chen*,  Tetrathienylethene-based porous framework composites for boosting photocatalytic antibacterial activity, Proc. Natl. Acad. Sci., 2025, 122, e2423052122.

(55) D. Wang, L. Shi*, and J. Li*, Revealing the iceberg beneath: A merge-net approach for designing multicomponent reticular solids, Matter, 2025, 8, 101949.

(54) S. Ma, L. Shi, Y. Zhong, H. Cao, Z. Yang, J. Yang, and Z. Chen*, Catenation Control in Stable Zr-MOFs for Fine-Tuning LNG-ANG-Related Methane Storage, Small, 2025, 21, 2409138.

(53) F.-W. Dong, Y. Chen, Q.-J. Cai, L.-Y. Ma, J. Yang, L. Shi, J. Zhu, D. Shao*, Switchable Magnetic Properties in a Hydrogen-Bonded Cobalt(II)-Organosulfonate Framework via Reversible Dehydration–Hydration, Cryst. Growth Des. 2025, 25, 10, 3464-3470.

(52) L. Huang, K.-H. Zhang, A.-N. Sun, B. Zhao,* L. Shi, J. Yang and D. Shao*, A cobalt(II)-terpyridine complex showing field-induced slow magnetic relaxation behavior via reverse spin-crossover, CrystEngComm, 2025, 

2024年

(51) S. Ma, Y. Lam, L. Shi, K. Ma, and Z. Chen*, Stable MOFs and Composites for Photocatalytic Antibacterial Applications, Trends in Chem. 2024, 6, 712-725

(50) H. Cao, L. Shi, Z. Xiong, H. Zhu, H. Wang, K. Wang, Z. Yang, H. Zhang, L. Liu, M. O'Keeffe, M. Li, and Z. Chen*, Two-Periodic MoS2-Type Metal-Organic Frameworks with Intrinsic Intralayer Porosity for High-Capacity Water Sorption, Adv. Mater. 2024, 2414362.

(49) S. Wu, Z. Ruan, Z. Tian*, L. Shi, J. Yang and D. Shao*, Construction, structures, and magnetic studies of two cobalt(II) and nickel(II) coordination polymers displaying bex topology. CrystEngComm, 2024, 26, 5850-5858

(48) S. Yang, Q. Zhang, Y. Zhang, T. Tan, J. Zhu, X. Yang, L. Shi, J. Yang, D. Shao*, Highly proton-conducting lanthanide metal–organic frameworks featuring       highly oxygenated ligands with slow magnetic relaxation or magnetocaloric effect, CrystEngComm, 2024, 26, 4181-4189.

(47) J. Zhu, K. Kumari, S. Chen, D. Shao*, J. Yang, L. Shi, S. Singh*, Y. Zhang, Magnetic and Porous Regulation in Cobalt(II) Hydrogen-Bonded Organic Framework via Supramolecular Isomerism, Cryst. Growth Des. 2024, 24, 3449-3457.

(46) J. Dong, L. Huang, L. Shi, J. Yang, Y. Wan and D. Shao*, Metalo Hydrogen-Bonded Organic Frameworks Constructed by Coordinated Chains for Magnetic and Proton-Conductive Bifunctionality, Inorg. Chem. 2024, 63, 17478-17487.

(45) L. Shi, Y. Zhong, H. Cao, H. Wang, Z. Xiong, K. Wang, H, Shen and Z. Chen*, A Hetero-Supermolecular-Building-Block Strategy for the Assembly of Highly Porous 3,12,24-Connected uru Metal–Organic Frameworks. Nat. Synth. 2024, 3, 1560-1566

(44) L. Shi, Z. Xiong, H. Wang, H. Cao and Z. Chen*, Quasicrystal Approximants in Isoreticular Metal-Organic Frameworks via Cairo Pentagonal Tiling. Chem. 2024, 10, 2464-2472

(43) L. Shi, K. O. Kirlikovali, Z. Chen* and O. K. Farha*, Metal-organic frameworks for water vapor adsorption. Chem. 2024, 10, 484-503.

(42) D.-Q. Wu, L. Shi, D. Shao*, M. Xia, Yuwei Liao, Y. Wu, J. Wen, B. Zhai, Dehydration-actuated single-molecule magnet behavior in a cyanide-bridged [Fe₂Co₂] cluster featuring zigzag structure. J. Mol. Struct., 2024, 1295, 136615.

(41) Hao Wang^† L. Shi^†, H. Cao, Z. Xiong, S. Ma, J. Pan* and Z. Chen*, Synthesis of an Iron-Based Metal-Organic Framework with Octahedral Cages for the Selective Capture of Sulfur Hexafluoride, CrystEngComm. 2024, 26, 1912-1916.

(40) S. Lei, L. Zhu, N. Xue, X. Xiao, L. Shi, D. Wang, Z. Liu, X. Guan, Y. Xie, K. Liu, L. Hu, Z. Wang, J. F. Stoddart and Q. Guo*, Angew. Chem. Int. Ed., 2024, 63, e202402255

(39) Z. Xiong, L. Gu, Y. Liu, H. Wang, L. Shi, X. Wu, L. Liu and Z. Chen*, Isoreticular Regulation of Two-Dimensional Redox-Active Covalent Organic Framework Cathodes for Enhanced Lithium-Ion Storage. CCS Chem., 2024, 6, 2835-2844.

2024年以前

(38) L. Shi, Z. Yang, F. Sha, Z. Chen*, Design, synthesis, and applications of functional zirconium-based metal-organic frameworks. Sci. China Chem. 2023, 66, 3383-3397.

(37) L. Shi*, J. Kobylarczyk, K. Dziedzic-Kocurek, J. J. Stanek, B. Sieklucka, R. Podgajny*. Site Selectivity for the Spin States and Spin Crossover in Undecanuclear Heterometallic Cyanido-Bridged Clusters. Inorg. Chem. 2023, 62, 7032-7044.

(36) Q. Zhang, S.-Y. Yang, S.-J. Chen, L. Shi*, J. Yang, Z. Tian, Z. Ruan, D. Shao*. Lanthanide dimers in coordination chains constructed by sole dicarboxylate ligand for single-molecule magnet behavior and magnetocaloric effect. J. Mol. Struct. 2023, 1294, 136349.

(35) Y.-L, Zhang, L. Shi*, G. Liu, J. Yang, D. Shao*. Hydrogen-bonded nickel(II)-organosulfonate framework: Thermal expansion behavior, proton conduction, and magnetic properties. J. Mol. Struct. 2023, 1292, 136131.

(34) D. Shao*, Y. Wan, J. Yang, Z. Ruan, J. Zhu and L. Shi*, Assembly of dysprosium(III) cubanes in metal-organic framework with ecu topology and slow magnetic relaxation, Dalton. Trans. 2023, 52, 17114-17118.

(33) Hao Wang^† L. Shi^†, Z. Xiong, S. Ma, H. Cao, S. Cai, Z. Qiao*, J. Pan* and Z. Chen*, A Two-Dimensional Metal-Organic Framework Assembled from Scandium-based Octahedral Cages for the Selective Capture of Sulfur Hexafluoride, Chem. Commun., 2023, 60, 2397-2400.

(32) Y. Wu, M. Tang, Z. Wang, L. Shi, Z. Xiong, Z. Chen*, J. L. Sessler* and F. Huang*, Pillararene incorporated metal-organic frameworks for supramolecular recognition and selective separation. Nat. Commun., 2023, 14, 4927.

(31) Z. Chen, K. O. Kirlikovali, L. Shi, O. K. Farha, Rational design of stable functional metal-organic frameworks. Mater. Horiz., 2023, 10, 3257-3268.

(30) D. Shao, L. Shi, G. Liu, J. Yue, S. Ming, X. Yang, J. Zhu, Z. Ruan, Metalo Hydrogen-Bonded Organic Frameworks Self-Assembled by Charge-Assisted Synthons for Ultrahigh Proton Conduction, Cryst. Growth Des., 2023, 23, 5035-5042

(29) F.-X. Xu, Y.-L. Li, X.-Q. Wei, D. Shao, L. Shi, H.-Y. Wei, X.-Y. Wang, Three new Mn^II-[Mo^III(CN)₇]^4- molecular magnets constructed from chiral bidentate chelating ligands. Dalton Trans., 2023, 52, 5575-5586.

(28) D. Shao*, Z. Ruan, J. Dong, L. Huang, M. You, J. Yang, L. Shi, Desolvation-induced magnetic switching from single-ion magnetism to spin-crossover in a halogen-functionalized cobalt(II) complex. J. Mol. Struct., 2023, 1294, 136548.

(27) D. Marcinkowski, M. Kubicki, V. Patroniak, T. Muzioł, S. Chorazy, L. Shi, M. Zychowicz, A. M. Majcher-Fitas, R. Podgajny, A. Gorczyński, Trityl-Based Lanthanide Supramolecular Assemblies Exhibiting Slow Magnetic Relaxation. Chem. Eur. J., 2023, 29, e2023006

(26) X.-M. Bu, S.-Y. Yang, Q. Zhang, L.-Z. Han, E.-S. Xiang, X.-C. Huang, L. Shi, D. Shao, Proton-conducting cobalt(II) hydrogen-bonded organic framework driven by coordinated water molecules with slow magnetic relaxation, J. Mol. Struct., 2023, 1286, 135544

(25) L. Shi, J. Kobylarczyk, K. Kwiatkowski, B. Sieklucka, S. Ferlay, R. Podgajny*. Binary and Ternary Core-Shell Crystals of Polynuclear Coordination Clusters via Epitaxial Growth. Cryst. Growth Des. 2022, 22, 3413-3420.

(24) D. Shao, J. Yang, X. Wei, L. Shi, M. You, X. Yang, Z. Ruan, Z. Tian, A proton conducting cobalt (II) spin crossover complex, Chem Asian J., 2022, 17, e202200949.

(23) Y. Zhou, H. Xiang, J. Zhu, L. Shi, W. You, X. Wei, Z. Tian, D. Shao, Synthesis, structure, magnetism and proton conductivity of a cyanide-bridged Ni^IICo^III framework, Polyhedron., 2022, 228, 116181.

(22) D. Shao*, S. Moorthy, P. Peng, W. Tang, L. Shi, Z. Wang, X. Wei* and S. K. Singh*, A Single-Ion Magnet Tape with Five-Coordinate Cobalt(II) Centers. Eur. J. Inorg. Chem., 2022, e202200354

(21) H. Li, Y. Sun, L. Shi, F. Chen, F. Shen, Y. Zhao and X. Wang*, Modulating the Structures and Magnetic Properties of Dy (III) Single-Molecule Magnets through Acid-Base Regulation. Inorg. Chem., 2022, 61, 2272-2283.

(20) D. Shao*, W. Tang, Z. Ruan, X. Yang, L. Shi, X. Wei*, Z. Tian, K. Kumari, S. K. Singh*, Water-driven reversible switching of single-ion magnetism and proton conduction in a dysprosium sulfonate. Inorg. Chem. Front., 2022, 9 6147-6157.

(19) D. Shao*, S. Moorthy, X. Yang, J. Yang, L. Shi, S. K. Sigh, Z. Tian, Tuning the structure and magnetic properties via distinct pyridine derivatives in cobalt(II) coordination polymers. Dalton Trans., 2022, 51, 695-704.

(18) L. Shi, D. Shao, X.-Q. Wei, K. R. Dunbar*, X.-Y. Wang*, Enhanced Single-Chain Magnet Behavior via Anisotropic Exchange in a Cyano-Bridged Mo^III-Mn^II Chain. Angew. Chem. Int. Ed. 2020, 59, 10379-10384.

(17) 史乐, 吴冬青, 卫晓琴, 王新益*, 基于 [Mo (CN)₇]^4-的分子磁性材料研究进展. 中国科学：化学. 2020, 50, 1637.

(16) L. Shi, D. Shao, F.-X. Shen, X.-Q. Wei, X.-Y. Wang*. A Three-Dimensional Mn^II-[Mo^III(CN)₇]^4- Ferrimagnet Containing Formate as a Second Bridging ligand. Chin. J. Chem. 2019, 37, 19-24.

(15) L. Shi, D. Shao, F.-X. Shen, X.-Q. Wei, X.-Y. Wang*. Syntheses, structures, and magnetic properties of three two-dimensional cobalt(II) single-ion magnets with a Co^IIN₄X₂ octahedral geometry. CrystEngComm, 2019, 21, 3176-3185.

(14) D. Shao, L. Shi, F.-X. Shen, X.-Q. Wei, O. Sato*, X.-Y. Wang*. Reversible On-off Switching of the Hysteretic Spin Crossover in a Cobalt(II) Complex via Crystal to Crystal Transformation. Inorg. Chem., 2019, 58, 11589-11598.

(13) F.-X. Shen, Q. Pi, L. Shi, D. Shao, H.-Q. Li, Y.-C. Sun, X.-Y. Wang*. Spin Crossover in Hydrogen-Bonded Frameworks of Fe^II Complexes with Organodisulfonate Anions. Dalton Trans., 2019, 48, 8815-8825.

(12) X.-Q. Wei, K.-J. Wang, D.-Q. Wu, D. Shao, L. Shi, F.-X. Shen, H.-Y. Wei*, X.-Y. Wang*. Two three-dimensional [Mo^ӀӀӀ(CN)₇]^4–-based magnets showing new topologies and ferrimagnetic ordering below 80 K. Dalton Trans., 2019, 48, 8843-8852.

(11) D. Shao, L. Shi, L. Yin, B.-L. Wang, Z.-X. Wang*, Y.-Q. Zhang*, X.-Y. Wang*. Reversible on-off switching of both spin crossover and single-molecule magnet behaviours via a crystal-to-crystal transformation. Chem. Sci., 2018, 9, 7986-7991.

(10) F.-X. Shen, H.-Q. Li, H. Miao, D. Shao, X.-Q. Wei, L. Shi, Y.-Q. Zhang*, X.-Y. Wang*. Heterometallic M^IILn^III (M = Co / Zn; Ln= Dy / Y) complexes with pentagonal bipyramidal 3d centres: syntheses, structures, and magnetic properties. Inorg. Chem., 2018, 57, 15526-15536.

(9) L. Shi, D. Shao, H.-Y. Wei*, X.-Y. Wang*. Two interpenetrated cobalt(II) metal-organic frameworks with guest dependent structures and field-induced single-ion magnet behaviors. Cryst. Growth Des. 2018, 18, 5270-5278.

(8) D. Shao, L. Shi, F.-X. Shen, X.-Y. Wang*. A cyano-bridged coordination polymer nanotube showing field-induced slow magnetic relaxation. CrystEngComm., 2017, 19, 5707-5711.

(7) D. Shao, L.-D. Deng, L. Shi, D.-Q. Wu, X.-Q. Wei, S.-R. Yang, X.-Y. Wang*. Slow Magnetic Relaxation and Spin Crossover Behaviour in a Bicomponent Ion-pair Cobalt(II) Complex. Eur. J. Inorg. Chem., 2017, 3862-3867.

(6) D.-Q. Wu, D. Shao, X.-Q. Wei, F.-X. Shen, L. Shi, D. Kempe, Y.-Z. Zhang, K. R. Dunbar*, X.-Y. Wang*. Reversible On-Off Switching of a Single-Molecule Magnet via a Crystal-to-Crystal Chemical Transformation. J. Am. Chem. Soc., 2017, 139, 11714-11717.

(5) D. Shao, L. Shi, H.-Y. Wei, X.-Y. Wang*, Field-Induced Single-Ion Magnet Behaviour in Two New Cobalt(II) Coordination Polymers with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine. Inorganics., 2017, 5, 90.

(4) D.-Q. Wu, D. Shao, X.-Q. Wei, F.-X. Shen, L. Shi, Y.-Q. Zhang, X.-Y. Wang*. Single-Ion Magnetism in Seven-Coordinate Yb^III Complexes with Distorted D_5h Coordination Geometry. Dalton Trans., 2017, 46, 12884-12892.

(3) D.-Q. Wu, D. Kempe, Y. Zhou, L.-D. Deng, D. Shao, X.-Q. Wei, L. Shi, K. R. Dunbar*, X.-Y. Wang*. Three-Dimensional Fe^II−[Mo^III(CN)₇]⁴⁻ Magnets with Ordering below 65 K and Distinct Topologies Induced by Cation Identity. Inorg. Chem., 2017, 56, 7182-7189.

(2) D. Shao, S.-L. Zhang, L. Shi, Y.-Q. Zhang*, X.-Yi Wang*. Probing the Effect of Axial Ligands on Easy-Plane Anisotropy of Pentagonal-Bipyramidal Cobalt(II) Single-Ion Magnets. Inorg. Chem., 2016, 55, 10859-10869.

(1) D. Shao, L. Shi, S.-L. Zhang, X.-H. Zhao, D.-Q. Wu, X.-Q. Wei, X.-Y. Wang*. Syntheses, structures, and magnetic properties of three new chain compounds based on the pentagonal bipyramidal Co(II) building block. CrystEngComm., 2016, 18, 4150-4157.