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First Author : Hui Zhu
Date of Publication : 2016-01-01
Journal : Advanced Synthesis & Catalysis
Affiliation of Author(s) : 化学与生命科学学院
Document Type : 期刊
Volume : Vol.358
Issue : No.23
Page Number : 3730-3735
ISSN : 1615-4150;1615-4169
Key Words : [2+2];cycloaddition;epoxides;silver;α,β-unsaturated;carbonyl;compounds;ynamides;ynol;ethers
Abstract : A regio- and stereoselective method for the synthesis of (E)-α,β-unsaturated carbonyls has been developed via a silver-catalyzed tandem epoxide rearrangement/intermolecular carbonyl-heteroalkyne metathesis. Various heteroalkynes including ynol ethers, yna
Translation or Not : no
Pre One : Copper-catalyzed borylative cyclization of 1,n-enynyl phosphates leading to five- to eight-membered cyclic 1,4-dienyl boronates.
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