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Palladium-Catalyzed Cross Addition of Terminal Alkynes to Aryl Ynamides: An Unusual trans-Hydroalkynylation Reaction

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First Author : Ge Liu

Date of Publication : 2014-01-01

Journal : Advanced Synthesis and Catalysis

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.356

Issue : No.16

Page Number : 3314-3318

ISSN : 1615-4169

Key Words : alkynes;hydroalkynylation;palladium;regio-;and;stereoselectivity;ynamides

Abstract : A palladium-catalyzed trans-hydroalkynylation of N-sulfonyl ynamides has been achieved for the first time, providing α-alkynylation adducts in high yields with excellent regio- and stereoselectivity. The resulting enyne products can serve as the useful pr

Translation or Not : no

Pre One : Photocatalytic acylarylation of unactivated alkenes with diaryliodonium salts toward indanones and related compounds.

Next One : Synthesis of Multisubstituted Enamides via Pd-Catalyzed Chloroallylation of Ynamides

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