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ChemInform Abstract: Direct Access to 2-Amino-5-azidomethylfurans Through Palladium-Catalyzed Azidative Cycloisomerization of Homoallenyl Amides.

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First Author : Huang, Qianwen

Date of Publication : 2016-01-01

Journal : ChemInform

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.47

Issue : No.51

ISSN : 0931-7597

Key Words : furan;derivatives;ring;closure;reactions,;annulation;reactions

Abstract : A novel azidative cycloisomerization of homoallenyl amides (I) and (III) using TmsN3 as the azidation reagent and a hypervalent iodine reagent as the oxidant giving a series of azidomethyl-furans (II) and (IV), resp., is presented.

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