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ChemInform Abstract: Palladium-Catalyzed Cross Addition of Terminal Alkynes to Aryl Ynamides: An Unusual trans-Hydroalkynylation Reaction.

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First Author : Ge Liu

Date of Publication : 2015-01-01

Journal : ChemInform

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.46

Issue : No.16

Key Words : C-C;bond;formation;amines;polyphenylalkyne;derivatives;(tolan;derivatives);catalysis,;phase-transfer;catalysis;e/z-selectivity

Abstract : The Pd catalyzed trans-hydroalkynylation of N-sulfonyl ynamides gives α-alkynylation products in high yields with excellent regio- and stereoselectivities.

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