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ChemInform Abstract: Copper-Catalyzed β-Selective Hydroborylation of Ynamides: A Facile Access to (E)-β-Alkenylamide Boronates.

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First Author : Yihui Bai

Date of Publication : 2015-01-01

Journal : ChemInform

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.46

Issue : No.46

Key Words : organo-boron;compounds;hydroboration,;boration;carboxylic;amides;alkenes;catalysis,;phase-transfer;catalysis;e/z-selectivity

Abstract : The entitled hydroboration of ynamides using bis(pinacolato)diboron as the borylating reagent, affords (E)-β-alkenylamide boronates in good yields with excellent regio- and stereoselectivity.

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