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ChemInform Abstract: Synthesis of (Z)-1-Thio- and (Z)-2-Thio-1-alkenyl Boronates via Copper-Catalyzed Regiodivergent Hydroboration of Thioacetylenes: An Experimental and Theoretical Study.

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First Author : Gangguo Zhu

Date of Publication : 2014-01-01

Journal : ChemInform

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.45

Issue : No.31

Key Words : organo-boron;compounds;e/z-selectivity;(incl.;e/z-isomerism);catalysis,;phase-transfer;catalysis;hydroboration,;boration;mercaptans,;thioethers;Editor's;choice

Abstract : For the first time a highly selective α- and β-borylation of thioacetylenes is developed by using bis(pinacolato)diboron (II) or pinacolborane (X).

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