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Palladium-Catalyzed Coupling of Haloalkynes with Ally) Acetate: A Regio- and Stereoselective Synthesis of (Z)-β-Haloenol Acetates.

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First Author : Xiaoyi Chen

Date of Publication : 2011-01-01

Journal : Journal of Organic Chemistry

Affiliation of Author(s) : 化学与生命科学学院

Document Type : 期刊

Volume : Vol.76

Issue : No.15

Page Number : 6338-6343

ISSN : 0022-3263

Key Words : ENOLS;*ALKYNES;*ACETATES;*HYDROCARBONS;*ORGANIC;chemistry

Abstract : A Pd-catalyzed coupling of haloalkynes with allyl acetate has been reported, providing a convenient method for the stereoselective synthesis of (Z)-β-haloenol acetates in good yields. The synthetic utility of this method is demonstrated by the formation o

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