A combined experimental and DFT study of active structures and self-cycle mechanisms of mononuclear tungsten peroxo complexes in oxidation reactions
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第一作者：Peng Jin
发表时间：2011-01-01
发表刊物：Journal of Molecular Structure
所属单位：物理化学研究所
文献类型：期刊
卷号：Vol.992
期号：No.1-3
页面范围：19-26
ISSN号：0022-2860
关键字：Active;structure;Tungsten;peroxo;complex;Density;functional;theory;(DFT);Hydrogen;peroxide;Adipic;acid
摘要：Tungsten peroxo complexes have been widely used in olefin epoxidation, alcohol oxidation, Baeyer–Villiger oxidation and other oxidation reactions, however, there is still not a unanimous viewpoint for the active structure of mononuclear tungsten peroxo co
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