Dehydrochlorination of 1, 1, 2-trichloroethane over SiO<sub>2</sub>-supported alkali and transition metal catalysts: Tunable selectivity controlled by the acid - base properties of the catalysts
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第一作者:Tong-Yang Song
发表时间:2018-01-01
发表刊物:Applied Catalysis B: Environmental
所属单位:物理化学研究所
文献类型:期刊
卷号:Vol.236
页面范围:368-376
ISSN号:0926-3373
关键字:Dehydrochlorination;vinylidene chloride;1, 2-dichloroethene;basicity-acidity;reaction mechanism.
摘要:Dehydrochlorination of 1, 1, 2-trichloroethane was performed on SiO supported alkali metal (Na. K, Cs) and transition metal (Mn, Ni, Zn) catalysts. The surface basicity or acidity of the catalyst exerted great influence on catalytic behaviors. The catalys
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