Catalytic Behaviors of Cr2O3 and CrO3/Cr2O3 Catalysts for Gas Phase Fluorination of 2-Chloro-1,1,1-trifluoroethane: Active Species and Catalyst Deactivation
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第一作者:Wang Yun
发表时间:2017-01-01
发表刊物:CHINESE JOURNAL OF INORGANIC CHEMISTRY
所属单位:物理化学研究所
文献类型:期刊
卷号:Vol.33
期号:No.1
页面范围:123-133
ISSN号:1001-4861
关键字:Cr2O3;CrO3/Cr2O3;fluorination;HCFC-133a;HFC-134a;catalyst deactivation
摘要:Two Cr-based model catalysts (Cr2O3 and CrO3/Cr2O3) were prepared respectively by precipitation and impregnation method and tested for gas phase fluorination of 2-chloro-1,1,1-trifluoroethane to synthesize 1,1,1,2-tetrafluoroethane. It was found that the
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