Catalytic dehydrofluorination of 1,1,1,3,3-pentafluoropropane to 1,3,3,3-tetrafluoropropene over fluorinated NiO/Cr2O3 catalysts
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第一作者:Luo, Jian-Wei
发表时间:2018-01-01
发表刊物:APPLIED SURFACE SCIENCE
所属单位:物理化学研究所
文献类型:期刊
卷号:Vol.433
页面范围:904-913
ISSN号:0169-4332
关键字:1,3,3,3-Tetrafluoropropene;1,1,1,3,3-Pentafluoropropane;Dehydrofluorination;NiO/Cr2O3 catalyst;Surface acidity;Acid-base synergy
摘要:Catalytic dehydrofluorination of 1,1,1,3,3-pentafluoropropane to 1,3,3,3-tetrafluoropropene was performed on a series of fluorinated NiO/Cr2O3 catalysts. The NiO/Cr2O3 catalysts were more active than the Cr2O3 because the new acid sites provided by NiF2 h
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