个人信息：

黄鑫，1988年出生，浙江永康人。化学与材料科学学院教授、博导、博后合作导师，校实验建设处专聘副处长；浙江省 “5246人才工程”青年优秀人才。2016年5月博士毕业于美国马萨诸塞大学，导师Wei Zhang教授。目前主要开展有机合成方法学，有机氟化学研究，先后在Angew. Chem. Int. Ed. （3篇）, Chem. Sci. （1篇）, Chem. Commun., Org. Lett., Adv. Synth. Catal., J Org. Chem.等国际重要期刊上发表SCI论文30余篇，相关研究成果多次被科学评论性网站X-mol、Synfact等科研评论性媒体进行专题报道。主持国家自然科学基金面上、青年以及浙江省自然基金等省部级以上项目4项，授权发明专利5项。获浙江省自然科学二等奖（第二完成人）。指导本科生获浙江省大学生化学竞赛一等奖4次。

科研项目：

7）省属高校基础科研费“省部级重大类科技计划培育项目”，2024-2025，主持（在研）

6）烯基鎓盐的加成型[2,3]-重排反应，浙江省自然科学基金探索项目，2025.01至2026.12，主持（在研）

5) 芳基碘(Ⅲ)/硫(Ⅳ)的无痕型[2,3]-重排反应，国家自然科学基金面上项目，2024.01至2027.12，主持（在研）

4) 原位构建高价碘型二氟烷基化亲电试剂及其相关反应研究，国家自然科学基金青年项目，2020.01至2022.12，主持（已结题）

3) 芳基高价碘促进的氟烷基反应研究，浙江省自然科学基金, 2019.01至2021.12，主持（已结题）

2) 自由基导向官能团的设计与开发，“先进催化材料”教育部重点实验室开放基金，主持（已结题）

1) 含氟专用化学品制备，浙江省领军型海外创新团队项目，参与（已结题）

横向项目：浙江康恩贝制药股份有限公司、巨化集团公司、浙江金拓机电有限公司

研究生指导：

已毕业：赵伟钊、张亚鸽、梁微健、周丽江、樊锁江、黄子懿、刘冰杰

在读：李泽彬、吉江涛、郑丁铭、张轩

讲授课程：

有机化学、普通化学三、有机化学实验、有机波谱分析（研究生）

代表论文：

1）Xin Huang,* Wei Zhang.* Recyclable Fluorous Cinchona Organocatalysts for Asymmetric Synthesis of Biologically Interested Compounds (Invited Feature Article). Chem. Commun. 2021, 10116.

2）Xin Huang, Weizhao Zhao, Yuchen Liang, Minghui Wang, Yalin Zhan, Yage Zhang, Lichun Kong, Zhi-Xiang Wang,* Bo Peng*. α-C–H Difluoroalkylation of Alkyl Sulfoxides via Intermolecular Pummerer Reaction.Org. Chem. Front. 2021, 8, 1280.

3）Xin Huang, Yage Zhang, Weijian Liang, Qifeng Zhang, Yaling Zhan, Lichun Kong, Bo Peng*. Dearomatization of Aryl Sulfoxides: A Switch between Mono- and Dual-Difluoroalkylation. Chem. Sci. 2020, 11, 3048.

4）Xin Huang, Yage Zhang, Chaoshen Zhang, Lei Zhang, Ying Xu, Lichun Kong, Zhi-Xiang Wang,* Bo Peng*. ortho Difluoroalkylation of Aryliodanes with Enol Silyl Ethers through a Rearrangement Enabled by a Fluorine Effect. Angew.Chem. Int. Ed. 2019, 58, 5956.

5)   Xin Huang,+ Yaling Zhan, Qifeng Zhang, Dongyang Li, Yage Zhang, Lichun Kong, Bo Peng*. Dearomative Dual-Functionalization of Aryl Iodanes. Angew. Chem. Int. Ed. 2019, 25, 17210.

6）Junsong Tian, Fan Luo, Chaoshen Zhang,  Xin Huang*, Yage Zhang, Lei Zhang, Licun Kong, Xin Hu, Zhi-Xiang Wang, Bo Peng*. Selective ortho C-H Cyanoalkylation of (Diacetoxyiodo)arenes via [3,3]-Sigmatropic Rearrangement. Angew. Chem. Int. Ed. 2018, 57, 9078.

7）Xin Huang, Weizhao Zhao, De-Li Chen, Yaling Zhan, TingtingZeng, Huiquan Jin, Bo Peng*. Benzyne-mediated trichloromethylation of chiral oxazolines. Chem. Commun. 2019, 55, 2070.

8）Xin Huang, Weizhao Zhao, Xiaofeng Zhang, Miao Liu, Vasconcelos, S. N. S.; Wei Zhang*. One-pot Fluorination and Organocatalytic Robinson Annulation for Asymmetric Synthesis of Mono- and Difluorinated Cyclohexenones. Molecules 2018, 23, 2251.

9）Xin Huang, Miao Liu, Jasinski, J. P., Bo Peng, Wei Zhang*. Recyclable Organocatalysts for a One-Pot Asymmetric Synthesis of 2-Fluorocyclohexanols Bearing Six Contiguous Stereocenters. Adv. Synth. Catal. 2017, 359, 1919.

10） Xin Huang, Miao Liu, Kenny Pham, Xiaofeng Zhang, Wen-Bin Yi, Jasinski, J. P., Wei Zhang*. Organocatalytic One-Pot Asymmetric Synthesis of Thiolated Spiro-γ-lactam Oxindoles Bearing Three Stereocenters. J. Org. Chem. 2016, 81, 5362.

11)  Xin Huang, Wen-Bin Yi, Wei Zhang*. One-Pot Reactions for Modular Synthesis of Polysubstituted and Fused Pyridines. Org. Lett. 2016, 18, 5640

12） Xin Huang, Kenny Pham, Xiaofeng Zhang, Wen-Bin Yi,  Jremy Hyatt, Tran, A., Jasinski, P. J., Wei Zhang*. Recyclable Organocatalyst-promoted One-pot Michael/Aza-Henry/Lactamization Reactions for Fluorinated 2-Piperidinones bearing Four Stereogenic centres. RSC Adv. 2015, 5, 71071.

13） Xin Huang, Kenny Pham, Wen-Bin Yi, Xiaofeng Zhang, Clamens, C., Hyatt, J., Jasinski, P. J., Tayvah, U., Wei Zhang*. Recyclable Organocatalyst-Promoted One-Pot Asymmetric Synthesis of Spirooxindoles Bearing Multiple Stereogenic Centers. Adv. Synth. Catal. 2015, 357, 3820.

14）Xin Huang, Wen-Bin Yi, Ahad, D., Wei Zhang*. Recyclable Cinchona Alkaloid Catalyzed Asymmetric Michael Addition Reaction. Tetrahedron Lett. 2013, 6064.

其他论文:

15) Mengyuan Chen,+ Yuchen Liang,+ Taotao Dong, Weijian Liang, Yanping Liu, Yage Zhang, Xin Huang, Lichun Kong, Zhi-Xiang Wang,* Bo Peng*. Z-Selective α-Arylation of α,β-Unsaturated Nitriles via [3,3]-Sigmatropic Rearrangement. Angew. Chem. Int. Ed. 2021, 60, 2339.

16) Lei Zhang,+ Jia-Ni He,+ Yuchen Liang,+ Mengjie Hu, Li Shang, Xin Huang, Lichun Kong, Zhi-Xiang Wang,* Bo Peng*. Selective [5,5]-Sigmatropic Rearrangement by Assembly of Aryl Sulfoxides with Allyl Nitriles. Angew. Chem. Int. Ed. 2019, 58, 5316.

17) Li Shang,+ Yonghui Chang,+ Fan Luo, Jia-Ni He, Xin Huang, Lei Zhang, Lichun Kong, Kaixiao Li, Bo Peng*. J. Am. Chem. Soc., 2017, 139, 4211.

18) De-Li Chen,+ Yan Sun,+ Mengyuan Chen, Xiaojin Li, Lei Zhang, Xin Huang, Yihui Bai, Fang Luo, Bo Peng.* Desulfurization of Diaryl(heteroaryl) Sulfoxides with Benzyne. Org. Lett. 2019, 21, 3986.

19) Yan Sun, Xin Huang, Xiaojin Li, Fan Luo, Lei Zhang, Mengyuan Chen, Shiya Zheng, Bo Peng*. Mild Ring Contractions of Cyclobutanols to Cyclopropyl Ketones via Hypervalent Iodine Oxidation. Adv. Synth. Catal. 2017, 360, 1082.

20) Xiaojing Li, Yan Sun, Xin Huang, Lei Zhang, Licun Kong, Bo Peng*. Synthesis of o-Aryloxy Triarylsulfonium Salts via Aryne Insertion into Diaryl Sulfoxides. Org. Lett. 2017, 19, 838.

专利申报：

3）黄鑫、陈孟源、彭勃，一种无金属催化直接合成联芳烃化合物的方CN110015942A

2）黄鑫、张亚鸽、许滢、彭勃，一种邻位含二氟亚甲基的芳基碘化合物及制备方法CN109776295A

1）黄鑫、张亚鸽、曾婷婷、靳慧全、许滢，一种制备α-芳基腈化合物的方法CN108409602A